Interest in bioenergy, in particular the use of biomass, has increased significantly in recent years due to increasing climate and economic concerns. As one of the key renewable energy sources, biomass plays an important role in the new energy framework. The aim of this research was to estimate the mass of woody husks and to check the influence of morphological features of selected hazelnut varieties on the energy parameters of waste biomass in the form of husk. Technical and elemental analyses were carried out on the husks of four varieties: ‘Kataloński’, ‘Olbrzymi z Halle’, ‘Olga’, and ‘Webba Cenny’, taking into account their weight, moisture content, heat of combustion (HHV and LHV), and pollutant emission factors (CO, CO2, NOx, SO2, Dust). Research has shown significant differences between the varieties in terms of their energy potential and pollutant emissions. The varieties ‘Olbrzymi z Halle’ and ‘Olga’ were found to have higher calorific values, making them more energy efficient. On the other hand, the varieties ‘Kataloński’ and ‘Webba Cenny’ showed lower dust and NOx emissions, which is beneficial from an environmental point of view. The analysis of the chemical and morphological composition of hazelnut husks allowed for the identification of relationships between morphological features and energy value and emission indicators. The conclusions from the conducted research suggest that hazelnut husks have significant potential as an energy raw material. The selection of an appropriate variety for energy crops should take into account both the calorific value and emission indicators, which will allow for the optimization of production processes and the promotion of sustainable development.